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Article Navigation> JOURNAL OF BEIJING INSTITUTE OF TECHNOLOGY> 2017> 26(2): 276-284
Jie Ouyang, Hongquan Yin, Qingshan Zhang, Yunzheng Li, Pengjun Yao. Synthesis and Characterization of Novel Biodegradable Poly Copolymers[J]. JOURNAL OF BEIJING INSTITUTE OF TECHNOLOGY, 2017, 26(2): 276-284. doi: 10.15918/j.jbit1004-0579.201726.0218
Citation: Jie Ouyang, Hongquan Yin, Qingshan Zhang, Yunzheng Li, Pengjun Yao. Synthesis and Characterization of Novel Biodegradable Poly Copolymers[J].JOURNAL OF BEIJING INSTITUTE OF TECHNOLOGY, 2017, 26(2): 276-284.doi:10.15918/j.jbit1004-0579.201726.0218
shu

Synthesis and Characterization of Novel Biodegradable Poly Copolymers

doi:10.15918/j.jbit1004-0579.201726.0218

  • 1. School of Chemical Engineering, Environment, Beijing Institute of Technology, Beijing 100081, China;
    2. Anhui Sealong Biotechnology Co., Ltd, Bengbu, Anhui 233316, China

  • Received Date:2016-09-07
    Abstract
  • Novel biodegradable aliphatic polyesters, poly(butylene succinate-co-triethylene glycol succinate) (P(BS-co-TEGS)) and poly(butylene succinate) (PBS), were synthesized through a two-step procedure of esterification and polycondensation with succinic acid and 1, 4-butanediol/triethylene glycol as raw materials as well as tetrabutyl titanate and diphenylphosphinic acid as the co-catalysts. The chemical structure and molecular weight of the copolymers were characterized by 1H nuclear magnetic resonance ( 1H NMR) and gel permeation chromatography (GPC), respectively. In addition, thermal properties, crystal structure and mechanical properties were also analyzed with various techniques. P(BS-co-TEGS) exhibited more excellent mechanical properties than PBS, especially in elongation at break. Meanwhile, the crystal structure and thermal stability of the P(BS-co-TEGS) have hardly changed. The crystallinity of P (BS-co-TEGS) was lower than that of PBS and decreased with the increase of mole ratio of triethylene glycol. With the increase of TEGS unit molar composition, the melting point ( T m), crystallization temperatures ( T c) and heat of fusion (Δ H m) of P(BS-co-TEGS) decreased, while glass transition temperature ( T g) increased.
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