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Article Navigation> JOURNAL OF BEIJING INSTITUTE OF TECHNOLOGY> 2001> 10(3): 322-325
LI Zhan xiong, OU Yu xiang, CHEN Bo ren. Synthesis of Two Furazano Azides[J]. JOURNAL OF BEIJING INSTITUTE OF TECHNOLOGY, 2001, 10(3): 322-325.
Citation: LI Zhan xiong, OU Yu xiang, CHEN Bo ren. Synthesis of Two Furazano Azides[J].JOURNAL OF BEIJING INSTITUTE OF TECHNOLOGY, 2001, 10(3): 322-325.
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Synthesis of Two Furazano Azides

  • School of Chemical Engineering and Materials, Beijing Institute of Technology, Beijing 100081, China

Funds:MinisterialLevelAdvancedResearchFoundation
  • Received Date:2000-07-04
    Abstract
  • bis(azidomethyl) 3,3′ bis(1,2,4 oxadiazole)(Ⅰ) and bis(azidoacetamino) oxazofurazan(Ⅱ) were synthesized. The structures of these two compounds have been identified by IR, 1H NMR, MS and elemental analysis. Azido groups were introduced into furazan derivatives and energetic materials of high nitrogen content and high enthalpy of formation can be obtained. The densities of compound Ⅰ and Ⅱ are relatively high. Compound Ⅰ is an azide of lower melting point, it is hopeful to be applied as energetic plastic additives.
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    • References (3)
  • [1]
    Shi Minda.A novel energetic material———organic azide[J]. Propellants and Explosives(in Chinese),1992,4:24-30.
    [2]
    Olofson R A,Michelman J S.Furazan[J]. J Org Chem,1965,30(6):1854-1859.
    [3]
    Sheremetev A B,Kulagina V O,Aleksandrova N S,et al.Aminofurazan as key synt hons for construction of high energetic materials[A]. OU Yuxiang.Proceedings of t he Third Beijing International Symposium on Pyrotechnics and Explosives[C]. Beijing:China Ordnance Society,1995.249-254.
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