Welcome to Journal of Beijing Institute of Technology
Advance Search
Volume 15Issue 1
.
Turn off MathJax
Article Contents
Article Navigation> JOURNAL OF BEIJING INSTITUTE OF TECHNOLOGY> 2006> 15(1): 111-114
SHAO Zi-qiang, WANG Wen-jun, WANG Fei-jun, WANG Ji-xun, TAN Hui-min. Nitration of Wood Cellulose in HNO3/Organic Solvent Medium[J]. JOURNAL OF BEIJING INSTITUTE OF TECHNOLOGY, 2006, 15(1): 111-114.
Citation: SHAO Zi-qiang, WANG Wen-jun, WANG Fei-jun, WANG Ji-xun, TAN Hui-min. Nitration of Wood Cellulose in HNO3/Organic Solvent Medium[J].JOURNAL OF BEIJING INSTITUTE OF TECHNOLOGY, 2006, 15(1): 111-114.
shu

Nitration of Wood Cellulose in HNO3/Organic Solvent Medium

  • School of Materials Science and Engineering,Beijing Institute of Technology,Beijing100081,China

Funds:theMinisterialLevelAdvancedResearchFoundation(40406030202)
  • Received Date:2004-05-21
    Abstract
  • A steam explosion pretreatment at various severities was applied to pure wood cellulose; the influences of steam pretreatment on the morphological structure, the hydrophilic property and viscosity-average molecular weight of cellulose were evaluated. The nitration of steam-exploded cellulose was carried out in the nitrating agent medium （HNO 3/organic solvent）. The performance indexes of nitrocellulose, prepared from original and steam exploded samples, were determined by using the polarized optical microscope. The results show that after pretreatment the reactivity of the three hydroxyl groups in anhydroglucose unit of cellulose is improved, and the nitrogen content and the uniformity of NC from steam exploded cellulose observably increas.
    • FullText(HTML)
  • loading
    • References (8)
  • [1]
    Shao Ziqiang. The appar atus and technique in the product ion process of nitrocellulose [M]. Beijing: Beijing Institute of T echnolog y Press, 2002. (in Chinese)
    [2]
    Gao Jie, Tang Guilie. Cellulose science [M]. Beijing:Science Press, 1999. (in Chinese)
    [3]
    Yamashiki T, Matsui T , Saitoh M, et al. Character ization of cellulose treated by the steam explosion method.Par t 1: Influence of cellulose resour ces on chang es inmorphology, degree of polymerizat ion, solubility and solid structur e [J]. British Polymer J, 1990, 22: 73-83.
    [4]
    Yamashiki T, Matsui T , Saitoh M, et al. Character ization of cellulose treated by the steam explosion method.Par t 2: Effects of treatment conditions on changes inmorphology, degree of polymerization, solubility in aqueous sodium hy drox ide and supermolecular structur e of softw ood pulp dur ing steam ex plosion [J]. British PolymerJ, 1990, 22: 121-128.
    [5]
    Shao Ziqiang , Tan Huimin, Xie Fang. Study on structural changes of natural celluloses treaded by the steamex plosion [J]. Cellulosic Fibre, 2001, 31(3); 1-3. (inChinese)
    [6]
    Pethrick R, Daw kins J V. Modern techniques for polymer character isation [M]. New York: John Wiley &Sons, 1999.
    [7]
    Focher B, Marzetti A, Conio G, et al. Fibers fr omDMAcLiCl so lutions of steam exploded wood [J]. J Applpolym, 1994, 51: 583-591.
    [8]
    Shao Ziqiang, Liao Shuangquan, Ma Feng guo, et al.Study on structural changes of soft w ood cellulose treatedby the steam ex plosion [J]. Polymer Materials Scienceand Eng ineering, 2002, 18(2); 120-122. (in Chinese)
    • Relative Articles
  • Supplements (0)
  • Cited By
  • 加载中

Catalog

    通讯作者:陈斌, bchen63@163.com
    • 1.

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (216) PDF downloads(1) Cited by()
    Proportional views
    Related

    Address:5 Zhongguancun South Street, Haidian District, Beijing

    Tel:86-10-68914374

    Email:blgywb@bit.edu.cn

    Copy Right © Journal of Beijing Institute of Technology

    Supported by:Beijing Renhe Information Technology Co. Ltd

    /

      Return
      Return
        Baidu
        map