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Article Navigation> JOURNAL OF BEIJING INSTITUTE OF TECHNOLOGY> 2006> 15(2): 221-224
HU Chang-wen, WANG Chun-xiu, LI Hui, NIU Xue-li, PAN Wan-long, GONG Yun. Synthesis and Structural Characterization of [Co（Q）2（H2O）2]（Q=8-Hydroxyquinoline Ion）[J]. JOURNAL OF BEIJING INSTITUTE OF TECHNOLOGY, 2006, 15(2): 221-224.
Citation: HU Chang-wen, WANG Chun-xiu, LI Hui, NIU Xue-li, PAN Wan-long, GONG Yun. Synthesis and Structural Characterization of [Co（Q）2（H2O）2]（Q=8-Hydroxyquinoline Ion）[J].JOURNAL OF BEIJING INSTITUTE OF TECHNOLOGY, 2006, 15(2): 221-224.
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Synthesis and Structural Characterization of [Co（Q）2（H2O）2]（Q=8-Hydroxyquinoline Ion）

  • School of Science, Beijing Institute of Technology, Beijing 100081, China

Funds:Sponsored bythe National Natural Science Foundation of China (20331010,20201007 and 90406002);Specialized Research Fund for theDoctoral Programof Higher Education(20030007014)
  • Received Date:2004-09-13
    Abstract
  • The single crystal of bi（8-hydroxyquinoline） bihydrated cobalt（Ⅱ） complex, [Co（Q） 2（H 2O） 2] （Q=8-hydroxyquinoline ion）, has been synthesized by general method and structurally characterized by single crystal X-ray diffraction. Crystal data: C 18H 16CoN 2O 4, monoclinic, C2/c, a=1.3362（4） nm, b= 0.9412（3） nm, c=1.3543（4） nm, β=109.672（4）°, Z=4. In the complex, Co（Ⅱ） ion is six-coordinated, forming a distorted octahedron. H-bonding and π-π stacking interaction play a significant role to form and stabilize the three-dimensional structure.
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    • References (12)
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