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WANG Dong, WANG Xiang-ke, GAO Hong, XING Yan. Welding nanofiber and microsphere with carbon dioxide[J]. JOURNAL OF BEIJING INSTITUTE OF TECHNOLOGY, 2013, 22(1): 126-129.
Citation: WANG Dong, WANG Xiang-ke, GAO Hong, XING Yan. Welding nanofiber and microsphere with carbon dioxide[J].JOURNAL OF BEIJING INSTITUTE OF TECHNOLOGY, 2013, 22(1): 126-129.

Welding nanofiber and microsphere with carbon dioxide

  • Received Date:2012-05-22
  • Two types of micro/nano structures, microsphere and nanofibre, were prepared by electro spinning technique and spray drying technique, with the soluble fluorinated poly (ether ether ketone) (3F-PEEK) as the matrix. The micro/nano structures were exhibited in the scanning electron microscope (SEM) micrograghs, and the separated nanofibre and microsphere were observed. The sizes of micro/nano structures were measured by the statistical analysis method. We designed experiments to connect up all the micro/nano structures to form new three dimensional micro/nano structures that were observed by SEM. In the experiments, supercritical carbon dioxide (CO 2) was selected as the welding solvent. A series of nanofibers were welded to form three dimensional netlike structures, and the particles were welded to form a porous film. The welding processes were studied by varying the exposure temperature, and the welding mechanism was discussed.
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  • [1]
    Eckert C A, Knutson B L, Debenedetti P G. Fluids as solvents for chemical and material processing[J]. Nature, 1996, 383: 313-318.
    [2]
    Novick B J D, Joseph M, Carbonell G. Deposition of thin polymeric films from liquid carbon dioxide using a high-pressure free-meniscus coating process[J]. Industrial & Engineering Chemistry Research, 2004, 43(2): 515-524.
    [3]
    Pai R A, Humayun R, Schulberg M T, et al. Mesoporous silicates prepared using preorganized templates in supercritical fluids[J]. Science, 2004, 303: 507-510.
    [4]
    Nielsen K A B D C, Glancy C W, Hoy K L, et al. Application of high solids coatings using supercritical fluids[J]. Polymer Materials Science Engineer, 1990, 63: 996-999.
    [5]
    DeSimone J M. Practical approaches to green solvents[J]. Science, 2002, 297: 799-803.
    [6]
    Sundararajan M, Yang S, Ogino K, et al. Supercritical CO 2processing for submicron imaging of fluoropolymers[J]. Chemistry of Materials, 2000, 12(1): 41-48.
    [7]
    Goldfarb D L, Pablo J J D, Nealey P F, et al. Aqueous-based photoresist drying using supercritical carbon dioxide to prevent pattern collapse[J]. Journal of Vacuum Science & Technology B, 2000, 18(6): 3313-3317.
    [8]
    Zhang X, Pham J Q, Ryza N, et al. Chemical-mechanical photoresist drying in supercritical carbon dioxide with hydrocarbon surfactants[J]. Journal of Vacuum Science & Technology B, 2004, 22(2): 818-825.
    [9]
    Krause B, Koops G H, van der Vegt N F A, et al. Ultralow-k dielectrics made by supercritical foaming of thin polymer films[J]. Advanced Materials, 2002, 14(15): 1041-1046.
    [10]
    Wind J D, Sirard S M, Paul D R, et al.Relaxation dynamics of CO 2diffusion, sorption, and polymer swelling for plasticized polyimide membranes[J]. Macromolecules, 2003, 36(17): 6442-6448.
    [11]
    Wind J D, Sirard S M, Paul D R, et al. Carbon dioxide-induced plasticization of polyimide membranes: pseudo-equilibrium relationships of diffusion, sorption, and swelling[J]. Macromolecules, 2003, 36(17): 6433-6441.
    [12]
    Abramowitz H, Shah P S, Green P F, et al. Welding colloidal crystals with carbon dioxide macromolecules[J]. Macromolecules, 2004, 37(19): 7316-7324.
    [13]
    Liu B J, Wei H, Chen C H, et al. Synthesis and characterization of trifluoromethylated poly(aryl ether ketone)s[J]. Polymers for Advanced Technologies, 2003, 14(3-5): 221-225.
    [14]
    Deitzel J M, Kleinmeyer J D, Hirvonen J K, et al. Controlled deposition of electrospun poly (ethylene oxide) fibers[J]. Polymer, 2001, 42(19): 8163-8170.
    [15]
    Deitzel J M, Kleinmeyer J D, Hirvonen J K, et al. The effect of processing variables on the morphology of electrospun nanofibers and textiles Polymer[J]. Polymer, 2001, 42(1): 261-272.
    [16]
    Reneker D H, Yarin A L, Fong H, et al. Bending instability of electrically charged liquid jets of polymer solutions in electrospinning[J]. Journal of Applied Physics, 2000, 87(9): 4531-4547.
    [17]
    Chen Y C, Dimonie V L, El-Aasser M S. Effect of interfacial phenomena on the development of particle morphology in a polymer latex system[J]. Macromolecules, 1991, 24(13): 3779-3787.
    [18]
    Lu Z H, Liu G J, Phillips H, et al. Palladium nanoparticle catalyst prepared in poly(acrylic Acid)-lined channels of diblock copolymer microspheres[J]. Nano Letters, 2001, 1 (12): 683-687.
    [19]
    Li Z B, Kesselman E, Talmon Y, et al. Multicompartment micelles from ABC miktoarm stars in water[J]. Science, 2004, 306: 98-101.
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